Zigzag Graphene Nanoribbon

Scanning tunneling microscopy picture of a zigzag graphene nanoribbon. Credit: Felix Fischer/Berkeley Lab

Technique Tunes Into Graphene Nanoribbons’ Electronic Potential

Ever considering that graphene— a thin carbon sheet simply one- atom thick– was found more than 15 years back, the marvel product ended up being a workhorse in products science research study. From this body of work, other scientists found out that slicing graphene along the edge of its honeycomb lattice produces one-dimensional zigzag graphene strips or nanoribbons with unique magnetic homes.

Many scientists have actually looked for to harness nanoribbons’ uncommon magnetic habits into carbon-based, spintronics gadgets that make it possible for high-speed, low-power information storage and info processing innovations by encoding information through electron spin rather of charge. Since zigzag nanoribbons are extremely reactive, scientists have actually grappled with how to observe and funnel their unique homes into a real-world gadget.

Now, as reported in the journal Nature, scientists at Lawrence Berkeley National Laboratory (Berkeley Lab) and UC Berkeley have actually established a technique to support the edges of graphene nanoribbons and straight determine their distinct magnetic homes.

Local Magnetic Ordering Along Zigzag Edge States Graphene Nanoribbons

Local magnetic purchasing along zigzag edge states (red and blue arrows) in nitrogen-doped graphene nanoribbons causes a splitting in energy of the nitrogen atom’s electrons. Credit: Felix Fischer/Berkeley Lab

The group co-led by Felix Fischer and Steven Louie, both professors researchers in Berkeley Lab’s Materials Sciences Division, discovered that by replacing a few of the carbon atoms along the ribbon’s zigzag edges with nitrogen atoms, they might discretely tune the regional electronic structure without interfering with the magnetic homes. This subtle structural modification even more allowed the advancement of a scanning probe microscopy strategy for determining the product’s regional magnetism at the atomic scale.

” Prior efforts to support the zigzag edge undoubtedly modified the electronic structure of the edge itself,” stated Louie, who is likewise a teacher of physics at UC Berkeley. “This issue has actually doomed efforts to access their magnetic structure with speculative strategies, and previously relegated their expedition to computational designs,” he included.

Guided by theoretical designs, Fischer and Louie developed a customized molecular foundation including a plan of carbon and nitrogen atoms that can be mapped onto the exact structure of the wanted zigzag graphene nanoribbons.

To construct the nanoribbons, the little molecular foundation are very first transferred onto a flat metal surface area, or substrate. Next, the surface area is carefully warmed, triggering 2 chemical deals with at either end of each particle. This activation action breaks a chemical bond and leaves an extremely reactive “sticky end.”

Each time 2 “sticky ends” fulfill while the triggered particles expanded on the surface area, the particles integrate to form brand-new carbon-carbon bonds. Ultimately, the procedure develops 1D daisy chains of molecular foundation. A 2nd heating action reorganizes the chain’s internal bonds to form a graphene nanoribbon including 2 parallel zigzag edges.

” The special benefit of this molecular bottom-up innovation is that any structural function of the graphene ribbon, such as the specific position of the nitrogen atoms, can be encoded in the molecular foundation,” stated Raymond Blackwell, a college student in the Fischer group and co-lead author on the paper together with Fangzhou Zhao, a college student in the Louie group.

The next difficulty was to determine the nanoribbons’ residential or commercial properties.

” We rapidly understood that, to not just determine however in fact measure the electromagnetic field caused by the spin-polarized nanoribbon edge states, we would need to attend to 2 extra issues,” stated Fischer, who is likewise a teacher of chemistry at UC Berkeley.

First, the group required to find out how to separate the electronic structure of the ribbon from its substrate. Fischer fixed the concern by utilizing a scanning tunneling microscopic lense suggestion to irreversibly break the link in between the graphene nanoribbon and the underlying metal.

The 2nd difficulty was to establish a brand-new method to straight determine an electromagnetic field at the nanometer scale. Thankfully, the scientists discovered that the nitrogen atoms replaced in the nanoribbons’ structure really functioned as atomic-scale sensing units.

Measurements at the positions of the nitrogen atoms exposed the particular functions of a regional electromagnetic field along the zigzag edge.

Calculations carried out by Louie utilizing calculating resources at the National Energy Research Scientific Computing Center (NERSC) yielded quantitative forecasts of the interactions that develop from the spin-polarized edge states of the ribbons. Microscopy measurements of the exact signatures of magnetic interactions matched those forecasts and verified their quantum residential or commercial properties.

” Exploring and eventually establishing the speculative tools that enable reasonable engineering of these unique magnetic edges unlocks to extraordinary chances of carbon-based spintronics,” stated Fischer, describing next-generation nano-electronic gadgets that depend on intrinsic residential or commercial properties of electrons. Future work will include checking out phenomena related to these residential or commercial properties in custom-made zigzag graphene architectures.

Reference: “Spin splitting of dopant edge state in magnetic zigzag graphene nanoribbons” by Raymond E. Blackwell, Fangzhou Zhao, Erin Brooks, Junmian Zhu, Ilya Piskun, Shenkai Wang, Aidan Delgado, Yea-Lee Lee, Steven G. Louie and Felix R. Fischer, 22 December 2021, Nature
DOI: 10.1038/ s41586-021-04201- y

This research study was supported by the DOE Office of Science. NERSC is a DOE Office of Science user center situated at Berkeley Lab.


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